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Does E. coli have some form of secondary metabolism?

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Yes they do. But they produces far less secondary metabolites as compared to other bacteria. Here is a detailed pathway seen in E. coli. KEGG PATHWAY: Biosynthesis of secondary metabolites. read more

E. coli can also be classified into hundreds of strains on the basis of different serotypes. E. coli O157:H7, for example, is a well-studied strain of the bacterium E. coli, which produces Shiga-like toxins, causing severe illness by eating cheese and contaminated meat. read more

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