He has, although not for the reason you think. The defining moment of Logan's life was at the Weapon X facility. read more
Old man Logan, who was tricked into killing most of the X-Men, stopped using his claws, but he wasn't in a PTSD state. Quite the contrary: he let it slide and came up with a new family and became pacifist. read more
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He does not seem to have any signs of PTSD whatsoever. Wolverine, however, is seen to be bothered by the killing. This is the reason he quits the 'team' of mutants in the first origins movie. His PTSD revolves around the atrocities he committed and saw being committed during the wars. read more