No, they are as different as oxygen that you breathe and oxygen in water that you drink. First: Iron is not a molecular compound, so you can not speak about iron molecules. read more
Pure iron is pretty much nonexistent in nature, the only known examples coming from iron meteorites. Most iron on earth is in some form of an iron oxide, aka iron ore. This ore is then shipped to refineries where it is made into iron alloys or steel by mixing it with other elements like manganese and carbon. read more
Iron is an element on the periodic table, and in both these cases we are referring to iron as the element, so they are essentially the same thing. Iron in your blood and iron in metal are both the same element, but they are in different chemical environments. read more