If you're talking about the undergraduate programs, then Duke will provide greater access to finance and consulting opportunities. read more
Yes, Duke sends a lot of students to finance and consulting but Chicago does too. Also, just remember that life is longer than you think and your first job is important but does not determine everything. read more
I would go to Duke. It is a slightly better school, and has a better reputation. Duke's campus is amazing, too (look at this: http://library.duke.edu/uarchives/images/buildings/progpix/Oldest_surviving_aerial_view_of_WC_view.JPG). University of Chicago has a nice campus too, but doesn't compare to Duke. read more