What causes molecules to have vibration states?
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A molecular vibration occurs when atoms in a molecule are in periodic motion while the molecule as a whole has constant translational and rotational motion. read more
As well as the selection rules that are strictly quantum phenomena pertaining to symmetry, we can get combination vibrations so that one molecule can vibrate in multiple modes, and the vibrational state of two adjacent bonds can be a proportioned mixture of each vibration. read more
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