As sodium is a stronger reducing agent (higher on activity series) than zinc, the reaction will not occur spontaneously; it will not occur without putting in some external energy. read more
So Zinc is capable of making plenty of complex ions and compounds. That’s beauty of d block elements. Given that Zn makes a Na2Zn(OH)2 compound, I would say ZnCl2 reacts with NaCl in the following manner. 2NaCl + ZnCl2 → Na2(ZnCl4) The IUPAC name would be Sodium tetrachlorozincate (II) Notice how the Zinc didn’t change its oxidation number. read more