For crystalline materials(rather say polycrystalline), when liquid begin to solidify then the atoms stop moving around much and starts to gather in smaller volume (get packed). read more
A grain boundary (GB) is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. read more
So each grain consists of either a single crystal or polycrystalline aggregate. The surface that separates individual grains from each other are called Grain Boundaries. The crystal orientation changes abruptly across the grain boundry. read more
A grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are 2D defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. read more