Fluorine is the most electronegative element because it has 5 electrons in it's 2P shell. The optimal electron configuration of the 2P orbital contains 6 electrons, so since Fluorine is so close to ideal electron configuration, the electrons are held very tightly to the nucleus. read more
Fluorine is the most electronegative element because the definition of electronegativity makes it so. The electronengativity scales are defined based on experimentally determined properties of the elements. Fluorine has appropriate values for all of the common scales to ensure it has the highest electronegativity. read more