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Types of Hybridization

Bonding-Pair vs Bonding
Bonding-Pair vs Bonding

Again we need a hybrid orbital for each atom and pair of non-bonding electrons. Ammonia has three hydrogen atoms and one non-bonded pair of electrons when we draw the electron-dot formula. In order to determine the hybridization of an atom, you must first draw the electron-dot formula.

LINEAR - AB2 e
LINEAR - AB2 e

1 Chemical Bonding II: Molecular Geometry and Hybridization of Atomic Orbitals Chapter 10 Linear 180o Trigonal planar 120o Tetrahedral 109.5o Trigonal Bipyramidal

source: wou.edu
Lone Pairs Distort Bond Angles
Lone Pairs Distort Bond Angles

Even with a lone electron pair and 2 sigma bonds, there are 3 electron regions, it is still referred to as sp2 hybridization. An example of a molecule with 2 sigma bonds and a lone pair of electrons is S0 2. Tetrahedral Molecular Geometry. With 4 sigma bonds and no lone pairs there are 4 electron regions and the molecular shape is tetrahedral.

Molecular Geometries of Molecules
Molecular Geometries of Molecules

Hybridization of Atomic Orbitals and the Shape of Molecules. If the four hydrogen atoms in a methane molecule (CH 4) were bound to the three 2p orbitals and the 2s orbital of the carbon atom, the H-C-H bond angles would be 90 o for 3 of the hydrogen atoms and the 4th hydrogen atom would be at 135 o from the others.

OCTAHEDRAL - SF6 (AB6) - BrF5 (AB5E)
OCTAHEDRAL - SF6 (AB6) - BrF5 (AB5E)

What is the hybridisation of $\ce{BrF5} ... What is the hybridisation in BrF5 ... the bonding in SF6 can be described using two, ...

TETRAHEDRAL - CH4 (AB4) - NH3 (AB3E)
TETRAHEDRAL - CH4 (AB4) - NH3 (AB3E)

Finally divide the whole by 2 & you will get the hybridization. Now for CH4 - C is the central atom & has 4 valence electrons. Four hydrogen atoms are bonded by four single bonds. So according to the trick 4+4 =8. Dividing 8 by 2 we get 4 i.e. sp3 (tetrahedral).

source: quora.com
Trigonal Bipyramidal (AB5)
Trigonal Bipyramidal (AB5)

Trigonal Bipyramidal Electronic ... Trigonal bipyramid electronic geometry 2. ... 4U molecule is SF 4 |Hybridization of S atom is sp3d. 3 Lewis Dot H C H H H

source: chem.tamu.edu
Valence Bond Theory (Hybrid Orbitals)
Valence Bond Theory (Hybrid Orbitals)

The valence bond theory states that atoms in a covalent bond share electron density through the overlapping of their valence atomic orbitals. This creates an area of electron pair density between the two atoms.

source: opentextbc.ca

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